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|Section8= }} Phosphoryl bromide, also known as phosphorus oxybromide, is an inorganic compound with the formula POBr3. It can be prepared via the slow addition of liquid bromine to phosphorus tribromide at 0 °C, followed by the slow addition of water and vacuum distillation of the resulting slurry. It is prepared according to the equation: 3 PBr5 + P2O5 → 5 POBr3〔Hönigschmid, Hirschbold-Wittner, Z. Anorg. Allg. Chem. 243, 355 (1940)〕〔Johnson, Nunn, J. Am. Chem. Soc. 63, 141 (1941); Booth, Seegmiller, Inorg. Synth. 2, 151 (1946)〕 ==Properties== Thin plates, faint orange tint, d 2.822. mp 56° (in hot water). bp758 193° (decomposes). Slowly hydrolyzes in water forming H3PO4 and HBr. Soluble in ether, benzene, chloroform, carbon disulfide, concentrated H2SO4. Store in sealed glass ampoules. 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Phosphoryl bromide」の詳細全文を読む スポンサード リンク
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